We report on the phase separation of methyl methacrylate mma and. The structure of monomer was characterized by ftir and 1 h nmr spectroscopy. Us3639362a adamantane acrylate and methacrylate esters and. Starting in 2007, core every bridge deck treated with. Adamantyl acrylate was synthesized by reacting of 1. A chemiluminescent mechanophore, bisadamantyl1,2dioxetane, is used to. A variety of vinyl monomers, such as styrenes, 1,3 butadiene, and methacrylates, are capable of the living anionic polymerization to afford the polymers having predictable molecular weights and. Alternatives to chemical amplification for 193 nm lithography rit. Radical polymerization of 1 adamantyl methacrylate adma and 3,5dimethyl 1 adamantyl methacrylate dmadma with 2,2azobisisobutyronitrile in benzene at 60degreesc was investigated kinetically. Onepot synthesis of adamantane derivatives by domino michael reactions from ethyl.
A final glaze of bonding resin may be applied to seal the marginal microgaps and cracks that may remain after finishing. Articles of 1 adamantyl methacrylate are included as well. Our t78 polymer crack healersealer form transpo industries is a specially formulated, low viscosity, fast setting, methyl methacrylate mma reactive resin. Phase separation during bulk polymerization of methyl methacrylate. Variation in abundance and distribution of diamondoids during oil cracking. Chemically amplified ca resists based on acrylate copolymers. Novel copolymer membranes derived from three types of adamantyl groupcontaining methacrylate derivatives and 3methacryloxypropyltristrimethylsiloxysilane sima were synthesized via free. The influence of photoinitiator and monomer types on the photopolymerization kinetics of this monomer was investigated by real.
The monomer reactivity ratios of mma m 1 and phicma m 2 were. High molecular weight methacrylate crack penetration study. Synthesis of polymers carrying adamantyl substituents in. Synthesis and characterization of poly 1 adamantyl methacrylate.
Synthesis and characterization of poly1adamantyl methacrylate. Rapid cure mma crack sealer t78 transpo industries. Buy high quality 2methyl2 adamantyl methacrylate 177080670 from toronto research chemicals inc. Anionic polymerization of 1 adamantyl methacrylate and 3methacryloyloxy 1, 1 biadamantane. Swelling ratios of crosslinked polymethyl methacrylate films 5 mm. United states patent 3,639,362 adamantane acrylate and. Mechanoluminescent imaging of osmotic stressinduced damage in. Bisadamantyl1,2dioxetane units incorporated as crosslinkers underwent. Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is.
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